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What type of orbital is the lone pair on the nitrogen found in?
In this molecule, the carbon that is directly attached to the nitrogen and the nitrogen itself are sp2 hybridized. This means that, within this bond, there are three sp2 orbitals present and the lone pair on the nitrogen occupies one of them.
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How many conjugated atoms are present in the given molecule?
A conjugated molecule is one that has its atoms arranged in such a way that allows p orbitals to lie parallel to each other. This allows for electron delocalization, which ultimately provides increased stability for the molecule. To find conjugated atoms, look for alternating single and multiple bonds. The circled carbon atoms are the only ones that are conjugated in this molecule.
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How many hydrogens are present in the given molecule?
Each alcohol group provides a hydrogen. Additionally, there are 24 "hidden" hydrogens. Refer to the photo below to see where these "hidden" hydrogens are located.
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List all functional groups in the given molecule.
The first carbon that is attached to the chlorine is an alkyl halide. The oxygen that is directly attached to two carbons is an ether. Lastly, the is a carboxylic acid.
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What is the general formula of an ether?
is the general formula of an ether.
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Which functional groups are present in the pictured molecule?
This picture shows each functional group in its own box.
1. Phenyl
2. Ketone
3. Amine
4. Acid anhydride
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Which of the following compounds has the molecular formula, ?
The molecular formula follows the rule regarding the molecular formula of alkenes:
. Therefore,
is the molecular formula for hexene.
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What kind of organic compounds contain an group?
By definition, alcohols are compounds that contain an (hydroxyl) group bonded covalently to the end of a hydrocarbon.
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Ethanol is characterized as what kind of alcohol?
Ethanol (or ethyl alcohol) is characterized as a primary alcohol since there is only one carbon-containing group that is directly attached to the carbon containing the group.
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What is the unsaturation number of cholic acid (shown), which is a steroid?
The unsaturation number is equal to the number of rings and pi bonds in a molecule. Here, there are 4 rings and 1 double bond, so the unsaturation number is 5. No formula is needed to calculate unsaturation number when a structural formula is given.
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What is the functional group present in the following molecule known as?
The molecule pictured above is known as an ether because it contains an oxygen atom within the sequence of a carbon chain. (An oxygen atom bonded to two carbons in a carbon chain).
Therefore the correct answer is ether. All other answer choices are carbonyls, meaning that they contain a carbon atom double bonded to an oxygen atom.
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Which of the following is an appropriate solvent for synthesizing Grignard reagents?
Grignard reagents are very strong bases, and therefore can be spoiled by protons. Grignard reagents are so basic in fact that any protic solvent will render them useless. Dimethyl ether is the only non-protic solvent, and is therefore the correct answer.
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I.
II.
III.
IV.
Which option gives the order of decreasing acidity of the molecules provided?
IV>III>I>II
The most acidic compound is option IV because it contains a carboxylic acid group which is the most acidic organic functional group. Phenols are weak acids. Alcohols in solution are slightly less acidic than water and therefore are slightly basic.
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What is the IUPAC name of the molecule shown?
The molecule's longest carbon chain has 6 carbons (thus, "hex-"), and the lack of double bonds makes it an alkane (thus "hexane"). The longest chain is a ring structure (thus "cyclohexane"), and the one branching group is a carbon chain consisting of one carbon and no double bonds (a "methyl" group). Because there are no other functional groups on the molecule there is no need to put a number before the location of the methyl group (thus "methylcyclohexane").
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What is the IUPAC name for the molecule shown?
The molecule's longest carbon chain has 5 carbons (thus, "pent"), and the lack of double bonds makes it an alkane (thus "pentane"). The one functional group is a bromine atom attached to carbon number 3 (whether read from left to right or right to left, the bromine is always on carbon number 3). Thus, the molecule is named "3-bromopentane."
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What is the IUPAC name for the compound shown?
The molecule's longest carbon chain has 5 carbons (thus, "pent"), and the one double bond makes it an alkENE (thus "pentene"). The longest chain is a ring structure (thus "cyclopentene"). Because the IUPAC rules automatically assign the location of the first double bond to carbons 1 and 2, there is no need for a number locand.
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What is the IUPAC name for the compound shown?
The molecule's longest carbon chain has 4 carbons (thus, "but"), and the presence of two double bonds makes it an alkENE, more specifically, a diene (thus "butadiene"). Because there is more than one way in which the double bonds can be arranged (between C1-C2 and C2-C3, or between C1-C2 and C3-C4), it's important to place locants indicating the lower-numbered carbon in each double bond.
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What is the IUPAC name for the molecule shown below?
The molecule's longest carbon chain has 5 carbons (thus, "pent-"), and the carbon-carbon double bond makes it an alkENE (thus "pentene"). The location of the double bond must be specified, and numbering the carbon chain to give the double bond the lowest numbers possible mean that it is numbered from right to left, putting the double bond between carbon 2 and carbon 3. This will put the methyl group on carbon 3.
Regarding stereochemistry, on carbon 2, the higher priority substituent is the methyl group. On carbon 3, the ethyl group is the higher priority. The higher priority substituents are on the same side of the double bond, and therefore the stereochemistry designation is "Z."
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What is the IUPAC name for the molecule shown?
The molecule's longest carbon chain has 6 carbons (thus, "hex-"), and the lack of carbon-carbon double bonds makes it an alkANE (thus "hexan-"). The presence of a hydroxyl group makes this molecule an alcohol (thus "hexanol"). The longest carbon chain is a ring structure (thus "cyclohexanol"), and the location of the alcohol group is assumed to be carbon 1 because it's the highest priority functional group on the molecule. The only other substituent is a methyl group, and numbering the carbon chain starting from the one containing the alcohol group and moving toward the methyl group puts the methyl group on carbon 2. Thus "2-methylcyclohexanol."
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What is the IUPAC name for the compound shown?
The molecule's longest carbon chain has 6 carbons (thus, "hex-"), and the presence of three double bonds makes it an alkENE, more specifically, a tri ene (thus "hexatriene"). Because there is more than one way in which the double bonds can be arranged it's important to place locants indicating the lower-numbered carbon in each double bond (1, 3, and 5 in this case).
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