Help with Organic Carbohydrates - Organic Chemistry
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Chemists and biochemists have many ways of representing sugars. Glucose, the most common hexose, is shown below in various linear and cyclic projections. Using the linear and cyclic projection of your choice, can you indicate which colored oxygen in the linear form corresponds to the circled hemiacetal oxygen once the cyclization reaction is complete?
Chemists and biochemists have many ways of representing sugars. Glucose, the most common hexose, is shown below in various linear and cyclic projections. Using the linear and cyclic projection of your choice, can you indicate which colored oxygen in the linear form corresponds to the circled hemiacetal oxygen once the cyclization reaction is complete?
This answer, regardless of your preference of projection type, is easiest to obtain using arrow pushing for the cyclization reaction to keep track of each carbon and oxygen:
The purple carbon in the linear projection ends in the circled hemiacetal position.
This answer, regardless of your preference of projection type, is easiest to obtain using arrow pushing for the cyclization reaction to keep track of each carbon and oxygen:
The purple carbon in the linear projection ends in the circled hemiacetal position.
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Which of the following structures represents the anomeric alpha ring structure of D-glucose?
Which of the following structures represents the anomeric alpha ring structure of D-glucose?
When converting a linear sugar to its ring form, a bond is formed between the oxygen attached to carbon 5 and the carbon at position 1. All hydroxyl groups that are not attached to the carbon in position 1 and are oriented to the right end up trans to the 
attached to carbon 5, while those that are in the left position end up cis to the 
attached to carbon 5.
If the hydroxyl group attached to carbon 1 ends up trans to the 
attached to carbon 5, the ring structure is considered alpha. If the hydroxyl group attached to carbon 1 is cis to the 
attached to carbon 5, the ring structure is considered beta.
The alpha ring structure of D-glucose bonds the carbon 1 hydroxyl group trans to the carbon 5 
group. The hyroxyl groups on carbons 2, 3, and 4 will be trans, cis, and trans with respect to the 
.
When converting a linear sugar to its ring form, a bond is formed between the oxygen attached to carbon 5 and the carbon at position 1. All hydroxyl groups that are not attached to the carbon in position 1 and are oriented to the right end up trans to the
If the hydroxyl group attached to carbon 1 ends up trans to the
The alpha ring structure of D-glucose bonds the carbon 1 hydroxyl group trans to the carbon 5
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Which of the following structures represents the anomeric alpha ring structure of D-galactose?
Which of the following structures represents the anomeric alpha ring structure of D-galactose?
When converting a linear sugar to its ring form, a bond is formed between the oxygen attached to carbon 5 and the carbon at position 1. All hydroxyl groups that are not attached to the carbon in position 1 and are oriented to the right end up trans to the attached to carbon 5, while those that are in the left position end up cis to the attached to carbon 5.
If the hydroxyl group attached to carbon 1 ends up trans to the attached to carbon 5, the ring structure is considered alpha. If the hydroxyl group attached to carbon 1 is cis to the attached to carbon 5, the ring structure is considered beta.
The alpha ring structure of D-galactose bonds the carbon 1 hydroxyl group trans to the carbon 5 group. The hyroxyl groups on carbons 2, 3, and 4 will be trans, cis, and cis with respect to the .
When converting a linear sugar to its ring form, a bond is formed between the oxygen attached to carbon 5 and the carbon at position 1. All hydroxyl groups that are not attached to the carbon in position 1 and are oriented to the right end up trans to the
If the hydroxyl group attached to carbon 1 ends up trans to the
The alpha ring structure of D-galactose bonds the carbon 1 hydroxyl group trans to the carbon 5
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Which of the following ring structures represents the anomeric alpha ring structure of D-mannose?
Which of the following ring structures represents the anomeric alpha ring structure of D-mannose?
When converting a linear sugar to its ring form, a bond is formed between the oxygen attached to carbon 5 and the carbon at position 1. All hydroxyl groups that are not attached to the carbon in position 1 and are oriented to the right end up trans to the attached to carbon 5, while those that are in the left position end up cis to the attached to carbon 5.
If the hydroxyl group attached to carbon 1 ends up trans to the attached to carbon 5, the ring structure is considered alpha. If the hydroxyl group attached to carbon 1 is cis to the attached to carbon 5, the ring structure is considered beta.
The alpha ring structure of D-mannose bonds the carbon 1 hydroxyl group trans to the carbon 5 group. The hyroxyl groups on carbons 2, 3, and 4 will be cis, cis, and trans with respect to the .
When converting a linear sugar to its ring form, a bond is formed between the oxygen attached to carbon 5 and the carbon at position 1. All hydroxyl groups that are not attached to the carbon in position 1 and are oriented to the right end up trans to the
If the hydroxyl group attached to carbon 1 ends up trans to the
The alpha ring structure of D-mannose bonds the carbon 1 hydroxyl group trans to the carbon 5
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Identify the aldose pictured, including its alpha or beta designation.
Identify the aldose pictured, including its alpha or beta designation.
The structure pictured is mannose because the hydroxyl groups at carbons 2, 3, and 4 are situated cis, cis, and trans (respectively) to the 
attached to carbon 5.
The mannose pictured is in alpha form because the hydroxyl group at carbon 1 is trans to the 
attached to carbon 5.
The structure pictured is mannose because the hydroxyl groups at carbons 2, 3, and 4 are situated cis, cis, and trans (respectively) to the
The mannose pictured is in alpha form because the hydroxyl group at carbon 1 is trans to the
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The Fischer projection pictured is a form of glucose. The carbon labeled "x" is the chiral carbon farthest away from carbon 1 and the hydroxyl group connected to carbon "x" is on the right. This fact designates that the glucose as what configuration?
The Fischer projection pictured is a form of glucose. The carbon labeled "x" is the chiral carbon farthest away from carbon 1 and the hydroxyl group connected to carbon "x" is on the right. This fact designates that the glucose as what configuration?
The chiral carbon farthest away from carbon 1 is designated as "D" if its hydroxyl group is on the right side in the Fischer projection. In other words, this is D-glucose because the hyroxyl group on carbon "x" is oriented to the right.
The chiral carbon farthest away from carbon 1 is designated as "D" if its hydroxyl group is on the right side in the Fischer projection. In other words, this is D-glucose because the hyroxyl group on carbon "x" is oriented to the right.
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What is the name of the aldose pictured in this Fischer projection?
What is the name of the aldose pictured in this Fischer projection?
The structure is D-ribose because it is a five-carbon aldose with the hydroxyl groups on carbons 2, 3, and 4 all on the right in the Fischer projection.
The structure is D-ribose because it is a five-carbon aldose with the hydroxyl groups on carbons 2, 3, and 4 all on the right in the Fischer projection.
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Which of the following statements is true regarding carbohydrates?
Which of the following statements is true regarding carbohydrates?
All of these statements are true. A carbohydrate is said to have a "D" conformation in its acyclic form when the alcohol group on the carbohydrate's top stereocenter is on the right side in a Fischer projection. Most carbohydrates that we deal with in organic chemistry are aldoses, which means that they contain an aldehyde. The anomeric carbon is the site of attachment from one monosaccharide to another, and can be used to create polysaccharides.
All of these statements are true. A carbohydrate is said to have a "D" conformation in its acyclic form when the alcohol group on the carbohydrate's top stereocenter is on the right side in a Fischer projection. Most carbohydrates that we deal with in organic chemistry are aldoses, which means that they contain an aldehyde. The anomeric carbon is the site of attachment from one monosaccharide to another, and can be used to create polysaccharides.
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What is the name of the following carbohydrate?
What is the name of the following carbohydrate?
Stereochemistry from second to fifth carbon is R, S, S, R, which indicates D-galactose. The Haworth structure is a six-membered ring, so the molecule is in its pyranose form. The molecule has its anomeric hydroxyl group pointing down, so it's the alpha anomer.
Stereochemistry from second to fifth carbon is R, S, S, R, which indicates D-galactose. The Haworth structure is a six-membered ring, so the molecule is in its pyranose form. The molecule has its anomeric hydroxyl group pointing down, so it's the alpha anomer.
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What is the name of the following molecule?
What is the name of the following molecule?
Stereochemistry from second to fifth carbon is R, S, R, R, which indicates D-glucose. The Haworth structure is a five-membered ring, so the molecule is in its furanose form. The molecule has its anomeric hydroxyl group pointing down, so it's the alpha anomer.
Stereochemistry from second to fifth carbon is R, S, R, R, which indicates D-glucose. The Haworth structure is a five-membered ring, so the molecule is in its furanose form. The molecule has its anomeric hydroxyl group pointing down, so it's the alpha anomer.
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Which of the following correctly describes a reducing sugar?
Which of the following correctly describes a reducing sugar?
A reducing sugar contains a hemiacetal/hemiketal group which means that in its open chain form it contains a ketone/aldehyde group. Sugars containing a free aldehyde group can be oxidized to a carboxylic acid, while sugars containing a free ketone group must be tautomerized to an aldehyde group through an ene-diol intermediate (shown below), and this can be oxidized to a carboxylic acid.
Reducing sugars are detectable with the formation of either a precipitate or a solution color change after addition of Tollens' Reagent, Benedict's solution, or Fehling's solution.
A reducing sugar contains a hemiacetal/hemiketal group which means that in its open chain form it contains a ketone/aldehyde group. Sugars containing a free aldehyde group can be oxidized to a carboxylic acid, while sugars containing a free ketone group must be tautomerized to an aldehyde group through an ene-diol intermediate (shown below), and this can be oxidized to a carboxylic acid.
Reducing sugars are detectable with the formation of either a precipitate or a solution color change after addition of Tollens' Reagent, Benedict's solution, or Fehling's solution.
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Alpha-D-glucopyranose:
Glucose (pictured) is defined as which of the following?
Alpha-D-glucopyranose:
Glucose (pictured) is defined as which of the following?
Glucose in its open chain form (shown below), has a free aldehyde group (an aldose), and it contains six carbons (a hexose). Together, glucose is shown to be an aldohexose.
Glucose in its open chain form (shown below), has a free aldehyde group (an aldose), and it contains six carbons (a hexose). Together, glucose is shown to be an aldohexose.
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Alpha-D-glucopyranose
Which of the labelled carbon atoms is the anomeric carbon?
Alpha-D-glucopyranose
Which of the labelled carbon atoms is the anomeric carbon?
The anomeric carbon is formed from the original carbonyl carbon in the straight-chain form of the molecule being attacked by a hydroxyl group to form a hemiacetal. This is seen as a carbon that is bonded to two oxygen atoms. In the case of glucose, the carbon labelled A is a hemiacetal, and is considered to be the anomeric carbon.
The anomeric carbon is formed from the original carbonyl carbon in the straight-chain form of the molecule being attacked by a hydroxyl group to form a hemiacetal. This is seen as a carbon that is bonded to two oxygen atoms. In the case of glucose, the carbon labelled A is a hemiacetal, and is considered to be the anomeric carbon.
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Shown below is the structure of a sugar molecule.
Which of the following is the most appropriate classification of this sugar?
Shown below is the structure of a sugar molecule.
Which of the following is the most appropriate classification of this sugar?
In this question, we're given the structure of a sugar molecule, and we're asked to identify which answer choice represents the correct identification of this molecule.
To answer this question, there are two things we need to look at. For one, we need to determine whether it is an aldehyde sugar (aldose) or a ketone sugar (ketose). The first carbon atom in the molecule (shown at the very top in the image) is shown as 
. This means that the carbon contains a double bond to the oxygen. Furthermore, since it also contains a bond to a hydrogen, we can conclude that this is an aldehyde functional group. Consequently, we know that this must be an aldose sugar.
Next, we need to look at the number of carbon atoms in the molecule. In the image shown in the question, there are a total of seven carbon atoms. Thus, this sugar would be classified as a heptose sugar (seven carbons) rather than a hexose sugar (six carbons).
Putting these two pieces of information together, we know that the sugar is both an aldose and a heptose. Therefore, this sugar is an aldoheptose.
In this question, we're given the structure of a sugar molecule, and we're asked to identify which answer choice represents the correct identification of this molecule.
To answer this question, there are two things we need to look at. For one, we need to determine whether it is an aldehyde sugar (aldose) or a ketone sugar (ketose). The first carbon atom in the molecule (shown at the very top in the image) is shown as
Next, we need to look at the number of carbon atoms in the molecule. In the image shown in the question, there are a total of seven carbon atoms. Thus, this sugar would be classified as a heptose sugar (seven carbons) rather than a hexose sugar (six carbons).
Putting these two pieces of information together, we know that the sugar is both an aldose and a heptose. Therefore, this sugar is an aldoheptose.
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