Elements and Atoms - High School Chemistry

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Question

If a neutron is added to the nucleus of an atom, which of the following has changed?

Answer

Isotopes are variations of an element that differ by the number of neutrons in the nucleus. Neutrons are neutrally charged, so adding or removing them from a nucleus does not alter the charge of the atom. The atomic number is the number of protons in an atom, and the mass number is the sum of both protons and neutrons in the nucleus. As a result, the mass number will change by adding a neutron.

The number of protons is equal to the atomic number of the element. Adding or subtracting protons will change the element's identity. Ions can be created by changing the number of electrons and isotopes can be created by changing the number neutrons, but changing the number of protons changes the element.

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Question

Which of the following will result in an ion?

Answer

Ions are atoms that have gained or lost electrons. This results in an atom with a charge. Atoms with a neutral charge have an equal number of protons and electrons. Changing the electron number will result in a charge on the atom.

For example, adding an electron to chlorine creates a chlorine anion.

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Question

Which of the following is a naturally occurring isotope of carbon-12?

Answer

Carbon is an element with six protons (atomic number six), and most commonly has six neutrons. This brings the total mass of carbon to twelve atomic mass units (12amu). There are isotopes of carbon with seven or eight neutrons, which are radioactive. These isotopes correspond to carbon-13 and carbon-14. The true atomic mass of carbon on the periodic table is 12.011amu, accounting for small contributions by these heavier isotopes.

Carbon-6, cabron-7, carbon-8, and carbon-9 imply isotopes with zero, one, two, and three neutrons respectively. Though these isotopes could theoretically exist, they would be extremely unstable and do not occur in nature.

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Question

Which element is isoelectronic with a bromide ion?

Answer

Two atoms are isoelectric if they each have the same number of electrons. In its ground state, bromine has 35 electrons, equal to the number of protons in order to have a neutral atom. In order to become a bromide ion, the bromine atom must gain one electron. This gives it a charge of negative one, but allows it to satisfy the octet rule, making it a very stable ion. With the ionization, the atom now has 36 electrons.

Krypton has atomic number 36, meaning that it will also have 36 electrons in its ground state.

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Question

Which of the following elements is isoelectronic with an oxygen ion?

Answer

Two atoms are isoelectric if they each have the same number of electrons. In its ground state, oxygen has 8 electrons, equal to the number of protons in order to have a neutral atom. In order to become a stable ion, the oxygen atom must gain two electrons. This gives it a charge of negative two, but allows it to satisfy the octet rule, making it a very stable ion. With the ionization, the atom now has 10 electrons.

Neon has atomic number 10, meaning that it will also have 10 electrons in its ground state.

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Question

Which of the following elements is isoelectronic with an isotope of fluorine?

Answer

Two atoms are isoelectric if they each have the same number of electrons. Ions of an element will vary in the number of electrons, but isotopes will vary in the number of neutrons only. In its ground state, fluorine has 9 electrons, equal to the number of protons in order to have a neutral atom. Any ground state isotopes of fluorine will also have 9 electrons, making them isoelectric.

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Question

Which of the following answer choices is not isoelectronic with the other atoms listed?

Answer

Isoelectronic atoms are atoms or ions that contain the same number of total electrons. is not isoelectronic with the rest of the ions and atoms listed because it contains a total of ten electrons, while the rest in the series contain thirty-six.

Positively charged ions (cations) are formed when electrons are removed from the outer shell of the atom. Removing a negatively charged electron gives the ion a positive charge. For example, the element rubidium, , in its ground state contains thirty-seven electrons. The ion contains one less, thirty-six, making it isoelectronic with krypton and the other ions and atoms in the series.

Negatively charge ions (anions) are formed when electrons are added to the outer shell of the atom. Adding a negatively charged electron gives the ion a negative charge. For example, ground state selenium, , contains thirty-four electrons. The ion , has two added electrons giving it a total of thirty-six electrons. The ion is isoelectronic with the other ions and atoms in the series.

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Question

Which is the isotopic notation for an isotope of an element with 19 protons and 20 neutrons.

Answer

The general isotopic notation is as follows: , where is the mass number, which is equal to the number of neutrons plus protons, and is the atomic number, which is equal to the number of protons. We know that the atomic number determines the identity of an element, thus an atom with 19 protons must be potassium . Following the isotopic notation mentioned above, our mass number is 39.

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Question

What is the isotopic notation for an isotope of an element with a mass number of 197 and 118 neutrons?

Answer

The general isotopic notation is as follows: , where is the mass number, which is equal to the number of neutrons plus protons, and is the atomic number, which is equal to the number of protons. We know that the atomic number determines the identity of an element, thus an atom with a mass number of 197 and 118 neutrons must have 79 protons. Thus the element is gold .

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Question

Identify the number of protons, neutrons, and electrons in a charged cation of aluminum (mass number = 27).

Answer

The atomic number of aluminum is 13, which means it has 13 protons. All atoms with 13 protons are called aluminum. The mass number of aluminum is 27 and is the sum of neutrons and protons. We simply subtract the number of protons from the mass number to get the number of neutrons. Normally there are an equal number of electrons and protons. But since this aluminum exists as an ion with a +3 charge, it has lost three electrons and has only 10 electrons.

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Question

What is the difference between chlorine-35 and chlorine-37?

Answer

Chlorine-35 and chlorine-37 are isotopes of each other. Isotopes are atoms of the same element that have different masses due to different numbers of neutrons.

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Question

An atom of iron has two electrons removed. Write out the ion in the form of where X is the atomic symbol and m is the charge. Identify this ion as either a cation, anion or neutral.

Answer

We know that the element is iron and that it is missing two electrons. This means that the atom has two less electrons than it has protons resulting in a charge of 2+. This can be written as

If an ion is positively charged it is a cation. If it is negatively charged (more electrons than protons) it is an anion.

The ion is a cation since it has a charge of 2+.

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Question

According to molecular orbital theory, which of the following is not a valid electron configuration?

Answer

We rank the order of orbital filling in order of increasing energy given the probability of an electron occupying a given space. Take into consideration the Aufbau principle, which states that electrons fill electron orbitals from most to least stable. Recall that eight electrons constitutes a full valence shell for all orbitals except for the first one, which has a maximum occupancy of two electrons. The order in which electrons are filled is as follows:

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Question

How many valence electrons does a fluorine atom have?

Answer

An atom's valence electrons are the electrons on the outermost shell surrounding the atom. For the first shell, the number of valence electrons can be at most 2. For all subsequent shells, the maximum is 8. To determine the number of valence electrons around a neutral atom, you match the atom with its group number. As you can see from the picture below, fluorine has a group number of 7. Therefore, it has 7 valence electrons.

Handmadegroupnumbers

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Question

Which of the following elements does not exist as a diatomic molecule?

Answer

A diatomic element is an element that will spontaneously bond with itself if it isn't already part of a compound. This is done to increase stability. The seven diatomic elements are hydrogen, oxygen, nitrogen, fluorine, chlorine, bromine, and iodine. Note that all of these except iodine are gasses at room temperature. Helium is a noble gas, which means it has a full valence shell. Helium does not need to bind to anything to increase its stability.

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Question

According to molecular orbital theory, which of the following is not a valid electron configuration?

Answer

We rank the order of orbital filling in order of increasing energy given the probability of an electron occupying a given space. Take into consideration the Aufbau principle, which states that electrons fill electron orbitals from most to least stable. Recall that eight electrons constitutes a full valence shell for all orbitals except for the first one, which has a maximum occupancy of two electrons. The order in which electrons are filled is as follows:

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Question

According to molecular orbital theory, which of the following is not a valid electron configuration?

Answer

We rank the order of orbital filling in order of increasing energy given the probability of an electron occupying a given space. Take into consideration the Aufbau principle, which states that electrons fill electron orbitals from most to least stable. Recall that eight electrons constitutes a full valence shell for all orbitals except for the first one, which has a maximum occupancy of two electrons. The order in which electrons are filled is as follows:

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Question

Which of the following quantum number sets is not possible?

Answer

Quantum numbers are used to describe the location of an electron within the electron cloud. The first quantum number corresponds to the energy level, which matches with the period of the periodic table in which the element is usually found. The second quantum number describes the electron subshell, corresponding to the s, p, d, and f subshells. The third quantum number tells the orbital within the subshell that holds the electron. Finally, the fourth quantum number describes the spin of the electron as either positive or negative. Each orbital can only carry two electrons.

The first quantum number is a positive integer:

The second quantum number is any integer greater than zero and less than the first quantum number:

The third quantum number is an integer between the value of the second quantum number and its inverse:

The final quantum number can only carry a value of positive or negative one-half:

The answer choice that gives an impossible set of quantum numbers has a negative second quantum number. The first and second quantum numbers will always be greater than or equal to zero.

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Question

Which quantum number provides information about the three-dimensional orientation of the atomic orbital in space (on which axis it lies)?

Answer

The location of a given electron is described by a set of four quantum numbers. Of these, the magnetic quantum number () gives the orientation of the orbital in three-dimensional space.

The principle quantum number, , gives the energy level of the electron. It essentially describes the size of the electron shell, and can be any integer value.

The azimuthal (angular momentum) quantum number, , refers to the subshell of the energy level. Each subshell has a different shape, corresponding to spdf configurations. can be any value from zero to .

The magnetic quantum number, , gives the orientation of the subshell given by the azimuthal quantum number. For example, a p orbital has three different orientations based on three different values for the magnetic quantum number. These values correspond to orientations along the x-axis, y-axis, or z-axis. Each orientation constitutes a different orbital and can hold exactly two electrons. The magnetic quantum number can be any integer greater than and less than , with the total number of possible orbitals given by .

is the electron spin quantum number. This number is used to distinguish between the two electrons in a single orbital.

() is not a quantum number. This is a formula that allows us to determine the possible values of for every principal quantum number.

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Question

What is the value of (principal quantum number) for a valence electron in a ground state calcium atom?

Answer

The ground state electron configuration for calcium is:

The question asks us to give the value for the valence electrons in calcium. Valence electrons are located in the outermost shell, the shell with the highest principle quantum number. For calcium, the outermost shell is 4s. The value that corresponds to 4s is .

The other answer choices are incorrect because they describe the value for the location of non-valence electrons.

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