Oxidation-Reduction Reactions - GRE Subject Test: Chemistry

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Question

Methane combusts in the presence of oxygen according to the following reaction:

Which of the following statements is true concerning the reaction?

Answer

By comparing the oxidation number of an atom as a reactant and its oxidation number as a product, we can determine if the atom has been oxidized or reduced. In increase in oxidation number indicates a loss of electrons, or oxidation. A decrease in oxidation number signals a gain of electrons, or reduction.

For electrochemistry, you should familiarize yourself with the traditional oxidation states of hydrogen , halogens , oxygen , and elemental atoms .

Carbon is initially in the form of methane, meaning that it is attached to four hydrogen atoms. The molecule is neutral, and each hydrogen has an oxidation number of . Carbon must have an initial oxidation state of in order to balance the molecular charge.

In the a product, carbon is attached to two oxygens, each with a charge of . Again, the molecule is neutral, so carbon must balance these charges. This means that carbon's final oxidation state is .

Since carbon went from an oxidation state of to , we can conclude that carbon has been oxidized in the reaction.

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Question

Based on the chemical equation given, which of the following compounds underwent reduction?

Answer

The type of chemical reaction given is called an oxidation-reduction reaction. In this type of reaction, there is a transfer of electrons from one element to another. The species gaining an electron is said to be reduced and the species losing an electron is oxidized. Manganese ion goes from a to a oxidation state. Therefore, manganese is reduced in the chemical reaction because it gains electrons from the compound being oxidized (iron).

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