Reaction Chemistry - GRE Subject Test: Chemistry

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Question

What is the net ionic equation for the ion exchange reaction between ferrous sulfate and calcium iodide? Assume all compounds are soluble.

Answer

First, we must know what ferrous sulfate is. Ferrous refers to , and sulfate has the formula . When we combine the two together we get .

Calcium is a divatent cation and iodide is a monovalent anion, so their salt is . The ion exchange reaction is then:

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Question

Select the net ionic equation from this molecular reaction:

Answer

The net ionic equation is derived by removing all spectator ions from the total ionic equation (in which all ions are listed). To put it another way, the net ionic equation involves only the ions that participate in a reaction which, in this case, is the precipitation of barium sulfate.

Begin by writing all aqueous compounds in their dissociated (ionic) forms.

Cancel out any ions that appear in equal quantities on both sides of the equation. In this case, we can cancel the nitrate and potassium ions.

This is our net ionic equation.

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Question

What is the balanced chemical equation for the combustion of butane ?

Answer

Combustion is the chemical reaction of a hydrocarbon with molecular oxygen, and it always produces carbon dioxide and water. Knowing the reactants and products, the unbalanced equation must be:

We start by balancing the hydrogens. Since there are 10 on the left and only 2 on the right, we put a coefficient of 5 on water.

Similarly, we balance carbons by putting a 4 on the carbon dioxide.

To find the number of oxygens on the right, we multiply the 4 coefficient by the 2 subscript on O (which gets us 8 oxygens) and then add the 5 oxygens from the 5 water molecules to get a total of 13. The needed coefficient for on the left would then have to be 13/2.

Because fractional coefficients are not allowed, we mutiply every coefficient by 2 to find our final reaction:

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Question

Determine whether or not solid aluminum reacts with aqueous zinc chloride. If it does, determine the balanced equation for the reaction.

Answer

When we check the activity series, it is fairly easy to see that aluminum metal is more reactive than zinc metal. So, in this case, the two metals undergo a redox reaction, where the aqueous is reduced to solid , and the solid is oxidized to aqueous . These charges are the common oxidation states for zinc and aluminum and should be memorized.

Because is the new species, it bonds with 3 ions. The unbalanced equation is:

We note that there are 2 chlorine atoms on the left and 3 chlorine atoms on the right. To balance, we use a 3 coefficient on the left and a 2 coefficient on the right. This gives a total of 6 chlorine atoms on eahc side.

However, now we have also increased the amounts of zinc and aluminum. We copy the necessary coefficients to balance those—2 for aluminum on the left, 3 for zinc on the right—and we are done:

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Question

What will be the coefficient for once the following equation is balanced?

Answer

In the unbalanced equation from the question, the reactant side contains two hydrogen atoms and one oxygen atom. On the product side of the equation, there are four hydrogens and two oxygen atoms. So for every oxygen atom there are two hydrogen atoms giving a ratio of (oxygen : hydrogen). Putting a coefficient of two in front of the water molecule on the reactant side of the equation balances the equation. Therefore, there are four hydrogen and two oxygen atoms on both sides of the balanced chemical equation.

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Question

When 15.5 grams of is used in the given reaction, how many moles of is produced?

Answer

We must first calculate the molecular weight of to use as a conversion factor:

For every mole of reacted, one mole of is produced.

Therefore, 0.1092 moles of is produced.

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Question

When 20.0 grams of is used in the given reaction, how many moles of is produced?

Answer

We must first calculate the molecular weight of to use as a conversion factor:

For every 1 mole of reacted, 2 moles of is produced.

Therefore,the number of moles of produced will be double the number of moles of used up in the reaction:

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Question

What is the smallest whole-number coefficient that can be designated to the water molecule that would balance the chemical equation given?

Answer

The number of atoms on the reactant side of the chemical equation are:

The number of atoms on the product side of the chemical equation are:

In a balanced chemical equation, the total number of atoms of each element must be equal on the reactant and product side of the chemical equation. There is one more oxygen and two more hydrogen atoms on the reactant side of the chemical equation. Giving the water molecule on the product side of the chemical equation would balance the chemical equation so that both sides contain six oxygens and five hydrogens:

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Question

What is the smallest whole number coefficient that can be designated to the molecule that would balance the chemical equation given?

Answer

The process of balancing a chemical equation is called "balancing by inspection" which is done by trial and error. The easiest way to approach the problem given is by balancing the species containing an element with the most complicated formula occurring in one reactant and one product. In this case, we can either begin by balancing the carbon or hydrogen in the propane molecule. Let's start with the carbon by adding a coefficient of 3 to the carbon dioxide molecule on the product side of the equation which gives:

Let's now balance the hydrogens by adding a coefficient of 4 to the product side of the equation:

Lastly, we can balance the number of oxygens in the reaction:

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Question

If of is used for the reaction given, how many grams of was formed?

Answer

Based on the molecular equation, for every 1 mole of reacted, 1 mole of is formed as a product. Using dimensional analysis, we can use this relationship to determine the moles of reacted:

We must calculate the molecular weight of :

To calculate the number of grams of , we need to convert the number of moles of to grams using the molecular weight as a conversion factor.

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Question

If of is used for the reaction given, how many grams of was formed?

Answer

Based on the molecular equation, for every 4 moles of reacted, 2 moles of is formed as a product:

We must calculate the molecular weight of :

To calculate the number of grams of , we need to convert the number of moles of to grams using the molecular weight as a conversion factor.

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Question

If of is formed during the reaction given, how many grams of was used?

Answer

Based on the molecular equation, for every 2 moles of formed, 1 mole of is reacted:

We must calculate the molecular weight of :

To calculate the number of grams of , we need to convert the number of moles of to grams using the molecular weight as a conversion factor.

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Question

If of is formed during the reaction given, how many grams of was used?

Answer

Based on the molecular equation, for every 3 moles of formed, 1 mole of is reacted:

We must calculate the molecular weight of :

To calculate the number of grams of , we need to convert the number of moles of to grams using the molecular weight as a conversion factor.

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Question

Which of the following is true regarding the solubility product constant, , for a reaction in the form:

Answer

To determine the solubility product constant, we only need the concentrations and coefficients of the ions. The effective concentration of any pure substance (solid, liquid, or gas) is equal to one by definition, so does not influence the value of . The equation for the solubility product constant of this reaction is:

The units of the solubility product constant will depend on the coefficients of the products. will be a constant for the reaction, and will not change as more solid dissolves or as the reaction progresses.

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Question

Methane combusts in the presence of oxygen according to the following reaction:

Which of the following statements is true concerning the reaction?

Answer

By comparing the oxidation number of an atom as a reactant and its oxidation number as a product, we can determine if the atom has been oxidized or reduced. In increase in oxidation number indicates a loss of electrons, or oxidation. A decrease in oxidation number signals a gain of electrons, or reduction.

For electrochemistry, you should familiarize yourself with the traditional oxidation states of hydrogen , halogens , oxygen , and elemental atoms .

Carbon is initially in the form of methane, meaning that it is attached to four hydrogen atoms. The molecule is neutral, and each hydrogen has an oxidation number of . Carbon must have an initial oxidation state of in order to balance the molecular charge.

In the a product, carbon is attached to two oxygens, each with a charge of . Again, the molecule is neutral, so carbon must balance these charges. This means that carbon's final oxidation state is .

Since carbon went from an oxidation state of to , we can conclude that carbon has been oxidized in the reaction.

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Question

Based on the chemical equation given, which of the following compounds underwent reduction?

Answer

The type of chemical reaction given is called an oxidation-reduction reaction. In this type of reaction, there is a transfer of electrons from one element to another. The species gaining an electron is said to be reduced and the species losing an electron is oxidized. Manganese ion goes from a to a oxidation state. Therefore, manganese is reduced in the chemical reaction because it gains electrons from the compound being oxidized (iron).

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Question

Consider the reaction reaction below.

A student allows the system to reach equilibrium and then removes two moles of hydrogen gas. Which of the following will be a result?

Answer

According to Le Chatelier's principle, when a system at equilibrium is disturbed, the system will react to restore equilibrium. In other words, it will seek to undo the stress. Here, if hydrogen gas is removed, the reaction will shift toward the reactants to re-form it. In the process, more nitrogen will be produced.

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Question

The initial concentrations of this reaction are listed below.

Based on these initial concentrations, which statement is true?

Answer

When given initial concentrations, we can determine the reaction quotient (Q) of the reaction. The reaction quotient is given by the same equation as the equilibrium constant (concentration of products divided by concentration of reactants), but its value will fluctuate as the system reacts, whereas the equilibrium constant is based on equilibrium concentrations.

By comparing the reaction quotient to the equilibrium constant, we can determine in which direction the reaction will proceed initially.

The reaction quotient with the beginning concentrations is written below.

This shows that the ratio of products to reactants is less than the equilibrium constant. Since Q is less than Keq in the beginning, we conclude that the reaction will proceed forward until Q is equal to Keq. In this manner, the denominator (reactants) will decrease and the numerator (products) will increase, causing Q to become closer to Keq.

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Question

A saturated solution of scandium hydroxide, which also contains solid scandium hydroxide, is treated with 0.1N HCl. The addition of acid will __________ the solubility of scandium hydroxide because of __________.

Answer

Scandium hydroxide dissociates according to this reaction.

As 0.1N HCl is added, it will quantitatively react with hydroxide anions to produce ScCl3 and water.

Hydroxide will be removed from the above equilibrium, and the system will compensate by shifting the equilibrium to the right, according Le Chatelier's principle. As the equilibrium shifts to the right, more solid scandium hydroxide is hydrolyzed, resulting in increased solubility.

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Question

A system contains iodine atoms that are in equilibrium with respect to the reaction below:

The volume of the system is suddenly reduced, leading to an increase in pressure. What effect will this have on the reaction?

Answer

Since the system is originally at equilibrium and a stress is applied, Le Chatelier's principle is to be considered. By increasing the total pressure, the reaction will move in the direction toward which there are less molecules of gas.

Looking at the original reaction there are two moles of gas on the left and only one on the right, indicating that the reaction will shift to the right if the pressure is increased.

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