Electron Affinity

Practice Questions

GRE Subject Test: Chemistry › Electron Affinity

Questions
5
1

Which of the given atoms has the lowest electron affinity?

2

Atoms have characteristic electronegativities and electron affinities. Which of the following best describes the difference between these two terms?

3

Which of the given atoms has the greatest electron affinity?

4

Electronegativity is an important concept in physical chemistry, and often used to help quantify the dipole moment of polar compounds. Polar compounds are different from those compounds that are purely nonpolar or purely ionic. An example can be seen by contrasting sodium chloride, NaCl, with an organic molecule, R-C-OH. The former is purely ionic, and the latter is polar covalent.

When comparing more than one polar covalent molecule, we use the dipole moment value to help us determine relative strength of polarity. Dipole moment, however, is dependent on the electronegativity of the atoms making up the bond. Electronegativity is a property inherent to the atom in question, whereas dipole moment is a property of the bond between them.

For example, oxygen has an electronegativity of 3.44, and hydrogen of 2.20. In other words, oxygen more strongly attracts electrons when in a bond with hydrogen. This leads to the O-H bond having a dipole moment.

When all the dipole moments of polar bonds in a molecule are summed, the molecular dipole moment results, as per the following equation.

Dipole moment = charge * separation distance

Electronegativity is associated with another function, electron affinity. What is true of electron affinity?

5

Which element would experience the greatest energy loss when a neutral atom in the gaseous phase gains one additional electron?

Return to subject