pH - AP Chemistry

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Question

What is the range of possible hydrogen ion concentrations in acidic solution?

Answer

For a solution to be acidic, it must have a pH between 1 and 6.99, since 7 is neutral; pH is –log(hydrogen ion concentration), the range of possible values is between 10–1 and 10–6.999.

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Question

What is the range of possible hydrogen ion concentrations in basic solution?

Answer

For a solution to be basic, it must have a pH between 8 and 14, since 7 is neutral; pH is –log(hydrogen ion concentration); the range of possible values is between 10–13 and 10–7.001.

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Question

What is the range of possible hydrogen ion concentrations in acidic solution?

Answer

For a solution to be acidic, it must have a pH between 1 and 6.99, since 7 is neutral; pH is –log(hydrogen ion concentration), the range of possible values is between 10–1 and 10–6.999.

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Question

What is the range of possible hydrogen ion concentrations in basic solution?

Answer

For a solution to be basic, it must have a pH between 8 and 14, since 7 is neutral; pH is –log(hydrogen ion concentration); the range of possible values is between 10–13 and 10–7.001.

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Question

What is the range of possible hydrogen ion concentrations in acidic solution?

Answer

For a solution to be acidic, it must have a pH between 1 and 6.99, since 7 is neutral; pH is –log(hydrogen ion concentration), the range of possible values is between 10–1 and 10–6.999.

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Question

What is the range of possible hydrogen ion concentrations in basic solution?

Answer

For a solution to be basic, it must have a pH between 8 and 14, since 7 is neutral; pH is –log(hydrogen ion concentration); the range of possible values is between 10–13 and 10–7.001.

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Question

What is the range of possible hydrogen ion concentrations in acidic solution?

Answer

For a solution to be acidic, it must have a pH between 1 and 6.99, since 7 is neutral; pH is –log(hydrogen ion concentration), the range of possible values is between 10–1 and 10–6.999.

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Question

What is the range of possible hydrogen ion concentrations in basic solution?

Answer

For a solution to be basic, it must have a pH between 8 and 14, since 7 is neutral; pH is –log(hydrogen ion concentration); the range of possible values is between 10–13 and 10–7.001.

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Question

What is the pH of a solution that has \[OH-\] 1 X 10–4 M?

Answer

pOH would be 4 (use –log \[OH–\]) and pH would be 14–pOH = 14 – 4 = 10

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Question

What is the pH of a solution with \[OH-\] = 4 X 10-6

Answer

\[OH-\] = 4 X 10-6

pOH = 5.4 — use –log \[OH–\] to find pOH

pH = 14– pOH = 8.6

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Question

What is the pH of a soution containing .0001 M HCl?

Answer

The pH of a solution is determined by taking the negative log of the concentration of hydrogen ions in solution. HCl is strong acid so it completely dissociates in solution. So adding .0001 M HCl is the same as saying that 1 *10-4 moles of H+ ions have been added to solution. The -log\[.0001\] =4, so the pH of the solution =4.

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Question

What is the pOH of a solution that has a \[H+\] = 3.2 X 10-7 mol?

Answer

\[H+\] = 3.2 X 10-7 mol

pH = -log \[H+\]

= 7 - log 3.2

= 7 -.505

=6.495

pOH = 14 - pH

= 7.5

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Question

Which of the following solutions contains the greatest number of H+ ions?

Answer

This question asks for the solution with the greatest number H+ ions, we can also approach this problem as if we are looking for the solution with the lowest pH. HCl is strong acid, therefore it will dissociate completely in solution. So the solution containing 0.010 mL of HCL contains 0.010 mL of H+ ions in solution, in addition to the H+ ions that are already in solution due to the auto-ionization of water. The only other solution that could have a pH less than 7 would be the one with 0.010 mL of CH3OH in excess water, becasue CH3OH is very slightly acidic. But since it is compared with an equal volume of HCl which is strong acid, it can be said that the most H+ ions will be found in the solution containing a small amount of strong acid, HCl.

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Question

What is the approximate pH of a 1.0 M solution of soluble CaCO3?

Answer

Calcium carbonate is a base since it's the salt of a strong base (NaOH) and a weak acid (carbonic acid). The only basic pH on the list is 8, making it the correct answer.

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Question

What is the pH of a 1 * 10–3M solution of H2CO3 acid? (pKa is 6.4)

Answer

The –log of the pKa will give you the Ka, so take the –log (6.4), which gives you approximately 4 * 10–7. The Ka expression is set up with products over reactants (hydrogen carbonate ion * hydrogen ion/carbonic acid). The undissociated carbonic acid is 0.001M, and you should use the variable 'x' to account for how much it dissociates and how many of the ions are produced. Ka = 4 * 10–7 = x2/0.001 ends up being your Ka expression, if you assume x is negligible compared to the original concentration of 0.001. Solving for x, you get 2 * 10–5. This is the hydrogen ion concentration. pH = –log (hydrogen ion concentration), so pH = –long(2 * 10–5), which is approximately 4.7.

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Question

If the Ksp of Mg(OH)2 is 1.2 * 10–11 and the magnesium ion concentration is 1.2 * 10–5M, at what pH does the Mg(OH)2 compound begin to precipitate?

Answer

The expression for Ksp is Ksp = \[Mg2+\]\[OH–\]2.

Thus, \[OH–\] = √(1.2 * 10–11)/(1.2 * 10–5)

\[OH–\] = 1 * 10–3

Thus, pH = –log(1 X 10–3) = 3

pH = 14 – 3 = 11

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Question

What is the pH of a 0.05M solution of hydroflouric acid?

Answer

The Ka = \[H+\]\[F–\]/\[HF\]. The beginning concentration of HF is given as 0.05, and we can use x as the variable that accounts for how much of the HF is lost, along with how much of the H+ and F– are formed.

Thus, Ka = _x_2/.05 if you use the approximation that x is negligible compared to the starting concentration of HF.

Solving for x, x = 1 * 10–3. This is the H+ ion concentration.

pH = –log(H+) = –log(1.0 * 10–3)) = 3

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Question

Which of the following will produce the solution with the lowest pH?

Answer

NaOH is a base, so that won't produce an acidic solution. Of the remaining acids, HCl and HI are strong acids, and HF is weak. HI is at a higher molarity, so it will produce the most acidic solution.

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Question

A chemist adds 625g of solid NaOH to 500mL of 16M H_2SO_4. What is the pH of the solution after it reaches equilibrium?

Answer

Consider the reaction of NaOH and H_2SO_4:

2NaOH+H_2SO_4\rightarrow Na_2SO_4\hspace{1 mm}+2H_2O

Now we will calculate the moles of H_2SO_4 in the solution prior to adding base.

500\hspace{1 mm}mL\times\frac{1\hspace{1 mm}L}{1000\hspace{1 mm}mL}\times\frac{16\hspace{1 mm}moles\hspace{1 mm}H_2SO_4}{1\hspace{1 mm}L}=8.00\hspace{1 mm}moles\hspace{1 mm}H_2SO_4

We will then calculate the amount of moles of H_2SO_4 that react with the base.

625\hspace{1 mm}g\hspace{1 mm}NaOH\times\frac{1\hspace{1 mm}mole\hspace{1 mm}NaOH}{40\hspace{1 mm}g\hspace{1 mm}NaOH}\times\frac{1\hspace{1 mm}mole\hspace{1 mm}H_2SO_4}{2\hspace{1 mm}moles\hspace{1 mm}NaOH}=7.81\hspace{1 mm}moles\hspace{1 mm}H_2SO_4

We will then calculate the remaining moles of H_2SO_4:

8.00\hspace{1 mm}moles\hspace{1 mm}H_2SO_4 -\hspace{1 mm}7.81\hspace{1 mm}moles\hspace{1 mm}H_2SO_4=0.19\hspace{1 mm}moles\hspace{1 mm}H_2SO_4

We will then calculate the new concentration of sulfuric acid:

\frac{0.19\hspace{1 mm}moles\hspace{1 mm}H_2SO_4}{0.5\hspace{1 mm}L}=0.38\hspace{1 mm}M

Sulfuric acid is a diprotic acid, so the hydrogen ion concentration is 0.76 M.

pH=-log[H^{+}]=-log(0.76)=0.12

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Question

A chemist adds 4.2\hspace{1 mm}g\hspace{1 mm}KOH to mL of water. What is the pH of the solution?

Answer

First, we will calculate [KOH] as follows:

\frac{4.2\hspace{1 mm}g\hspace{1 mm}KOH}{500\hspace{1 mm}mL}\times\frac{1000\hspace{1 mm}mL}{1\hspace{1 mm}L}\times\frac{1\hspace{1 mm}mole\hspace{1 mm}KOH}{56.1\hspace{1 mm}g\hspace{1 mm}KOH}=1.497\times10^{-1}\hspace{1 mm}M

Now we will calculate the pOH:

pOH=-log[OH^-]

In solution KOH_{(s)}\rightarrow K^{+}{(aq)}+OH^{-}{(aq)}, so [KOH]=[OH^-].

pOH=-log[1.497\times 10^{-1}]=8.248\times 10^{-1}

pH=14-pOH=14-0.8248=13.18

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