AP Chemistry › Reaction Mechanisms
Consider the following mechanism:
A + B -> R + C (slow)
A + R -> C (fast)
Which of the following is true?
For the reaction NO2 (g) + CO (g) -> NO (g) + CO2 (g), the reaction was experimentally determined to be Rate = k\[NO2\]2. If the reaction has the following mechanism, what is the rate limiting step, and why?
Step 1: 2 NO2 -> NO3 + NO (slow)
Step 2: NO3 + CO -> NO2 + CO2 (fast)
A possible mechanism for the overall reaction Br2 (g) + 2 NO (g) -> 2 NOBr(g) is
The rate law for the formation of NOBr based on this mechanism is rate = .
Based on the figure above, what arrows corresponds to the activation energy of the rate limiting step and the energy of reaction? Is the reaction endo- or exothermic?